Air pollutants are negatively associated with vitamin D-synthesizing UVB radiation intensity on the ground.

Atmospheric levels of pollutants may reduce the UVB intensity at the earth's surface, with a subsequent reduction in cutaneous vitamin D synthesis. We investigated the association of various pollutants with UVB intensity on the ground. Four-year data obtained from four weather stations from across Kuwait were analyzed by median regression. Pollutants that were negatively associated with UVB were [ß (95% CI)]: benzene [- 2.61 (- 4.13, - 1.09)], ethyl-benzene [- 2.20 (- 3.15, - 1.25)], ozone [- 0.23 (- 0.28, - 0.17)], nitric oxide [- 0.11 (- 0.15, - 0.06)], sulfur dioxide [- 0.10 (- 0.17, - 0.04)] and particulate matter PM10 [- 0.002 (- 0.003, - 0.002)]. Pollutants that were negatively associated with the UVB/UVA ratio were [ß (95% CI)]: benzene [- 15.57 (- 24.94, - 6.20)], nitric oxide [- 0.53 (- 0.81, - 0.25)], ozone [- 0.38 (- 0.70, - 0.06)], and total hydrocarbon [- 0.02 (- 0.04, - 0.01)]. Furthermore, benzene and nitric oxide levels were higher in the morning and evening hours, which are the times of most solar exposure in this region due to high temperature during midday. In addition to other known factors, attenuation of UVB by these pollutants may contribute to lower vitamin D levels in populations. In addition to direct public health hazard, these pollutants may contribute to the very high prevalence of VDD in this region.

Numerical simulation of gas dispersion from rooftop stacks on buildings in urban environments under changes in atmospheric thermal stability.

The prediction of dispersion of gases emitted from rooftop stacks in a built environment is important for preventing or minimizing their harmful effects on human health. In this study, the wind flow and dispersion of exhaust gas emitted from rooftop stacks on buildings in an urban environment under different atmospheric thermal stabilities were investigated using numerical simulations. The wind flow field and dispersion contaminants were simulated using a computational fluid dynamics model with the k-ε turbulent schemes being resolved by the Reynolds-averaged Navier-Stokes approach. An isolated building was modeled under conditions of varying thermal stratification of the boundary layers (neutral, unstable, and stable conditions). The diffusion flow field within the building wake zone was investigated for various stack sites (center, right side, and left side). Experiments were conducted in a wind tunnel to validate the numerical simulation results, by using the data qualitatively and quantitatively. The numerical simulation results were consistent with the experimental observations. The results indicated that the pollutant concentration of the plume spread was high near the stack and decreased with increasing distance from the stack. Under stable conditions, the flow motion and separation increased in the wake zone, and the pollutant concentration of the lateral spread at the average human height decreased. Under unstable conditions, the flow of the vortex circulation was fast and strong, and the pollutant concentration of the vertical spread was high.

Modeling gaseous emissions and dispersion of two major greenhouse gases from landfill sites in arid hot environment.

As waste production exponentially increases, landfill continues to be the common method of waste disposal. Landfills represent significant anthropogenic sources of methane (CH4) and carbon dioxide (CO2); the main constituents of greenhouse gases (GHGs) resultant from microbial decomposition of organic waste. In the present study, ISC-AERMOD dispersion model was employed to estimate the release and dispersion rates of CH4 and CO2 from major landfill sites across Kuwait under different seasonal conditions. Results revealed that dispersions of CH4 and CO2 were influenced by the dominant northwestern and southeastern wind directions and thus, the dispersion of CH4 and CO2 extended predominantly toward northeastern direction. In terms of seasonal variation, the maximum concentrations of CH4 and CO2 were detected in winter and spring seasons, close to the landfill zone, and the dispersion of CH4 and CO2 fluxes during winter and spring seasons was longer than that during summer and fall seasons. Consequently, residential areas close to the disposal sites were exposed to higher concentrations of CH4 and CO2 gases during winter and spring. The findings of this study can serve as the basis for selecting suitable landfill locations under desert climatic conditions as determined by the distances over which gaseous emissions can diffuse.

Stochastic analysis of concentration field in a wake region.

INTRODUCTION: Identifying geographic locations in urban areas from which air pollutants enter the atmosphere is one of the most important information needed to develop effective mitigation strategies for pollution control. MATERIALS AND METHODS: Stochastic analysis is a powerful tool that can be used for estimating concentration fluctuation in plume dispersion in a wake region around buildings. Only few studies have been devoted to evaluate applications of stochastic analysis to pollutant dispersion in an urban area. This study was designed to investigate the concentration fields in the wake region using obstacle model such as an isolated building model. We measured concentration fluctuations at centerline of various downwind distances from the source, and different heights with the frequency of 1 KHz. Concentration fields were analyzed stochastically, using the probability density functions (pdf). Stochastic analysis was performed on the concentration fluctuation and the pdf of mean concentration, fluctuation intensity, and crosswind mean-plume dispersion. RESULTS: The pdf of the concentration fluctuation data have shown a significant non-Gaussian behavior. The lognormal distribution appeared to be the best fit to the shape of concentration measured in the boundary layer. We observed that the plume dispersion pdf near the source was shorter than the plume dispersion far from the source. CONCLUSION: Our findings suggest that the use of stochastic technique in complex building environment can be a powerful tool to help understand the distribution and location of air pollutants.

Assessment of denitrification gaseous end-products in the soil profile under two water table management practices using repeated measures analysis.

The denitrification process and nitrous oxide (N2O) production in the soil profile are poorly documented because most research into denitrification has concentrated on the upper soil layer (0-0.15 m). This study, undertaken during the 1999 and 2000 growing seasons, was designed to examine the effects of water table management (WTM), nitrogen (N) application rate, and depth (0.15, 0.30, and 0.45 m) on soil denitrification end-products (N2O and N2) from a corn (Zea mays L.) field. Water table management treatments were free drainage (FD) with open drains and subirrigation (SI) with a target water table depth of 0.6 m. Fertility treatments (ammonium nitrate) were 120 kg N ha(-1) (N120) and 200 kg N ha(-1) (N200). During both growing seasons greater denitrification rates were measured in SI than in FD, particularly in the surface soil (0-0.15 m) and at the intermediate (0.15-0.30 m) soil depths under N200 treatment. Greater denitrification rates under the SI treatment, however, were not accompanied with greater N2O production. The decrease in N2O production under SI was probably caused by a more complete reduction of N2O to N2, which resulted in lower N2O to (N2O + N2) ratios. Denitrification rate, N2O production and N2O to (N2O + N2) ratios were only minimally affected by N treatments, irrespective of sampling date and soil depth. Overall, half of the denitrification occurred at the 0.15- to 0.30- and 0.30- to 0.45-m soil layers, and under SI, regardless of fertility treatment level. Consequently, sampling of the 0- to 0.15-m soil layer alone may not give an accurate estimation of denitrification losses under SI practice.

Environmental and agronomic implications of water table and nitrogen fertilization management.

Nitrate (NO3-) pollution of surface and subsurface waters has become a major problem in agricultural ecosystems. Field trials were conducted from 1996 to 1998 at St-Emmanuel, Quebec, Canada, to investigate the combined effects of water table management (WTM) and nitrogen (N) fertilization on soil NO3- level, denitrification rate, and corn (Zea mays L.) grain yield. Treatments consisted of a combination of two water table treatments: free drainage (FD) with open drains at a 1.0-m depth from the soil surface and subirrigation (SI) with a design water table of 0.6 m below the soil surface, and two N fertilizer (ammonium nitrate) rates: 120 kg N ha(-1) (N120) and 200 kg N ha(-1) (N200). Compared with FD, SI reduced NO3(-)-N concentrations in the soil profile by 37% in spring 1997 and 2% in spring 1998; and by 45% in fall 1997 and 19% in fall 1998 (1 mg NO3(-)-N L(-1) equals approximately 4.43 mg NO3- L(-1)). The higher rate of N fertilization resulted in greater levels of NO3(-)-N in the soil solution. Denitrification rates were higher in SI than in FD plots, but were unaffected by N rate. The N200 rate produced higher yields than N120 in 1996 and 1997, but not 1998. Corn yields in SI plots were 7% higher than FD plots in 1996 and 3% higher in 1997, but 25% lower in 1998 because the SI system was unable to drain the unusually heavy June rains, resulting in waterlogging. These findings suggest that SI can be used as an economical means of reducing NO3- pollution without compromising crop yields during normal growing seasons.